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Classic Oils Anti-Freeze Safety Data Sheet

Compilation date:  05/03/2021

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name:  Classic Oils 2-Year Blue Anti-Freeze

Product code:  N/A

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture:  PC4: Anti-Freeze and de-icing products.

1.3. Details of the supplier of the safety data sheet

Company name:  Classic Oils Ltd
Building 96
The Lubricant Store Bicester Heritage
Buckingham Road
Bicester
Oxon
OX26 8AL
United Kingdom
Tel:  01869 227062

Email:   sales@classic-oils.net

1.4. Emergency telephone number

Emergency tel:  01869 227062

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP:  Acute Tox. 4: H302; STOT RE 2: H373
Most important adverse effects:  Harmful if swallowed. May cause damage to organs through prolonged or repeated exposure ([oral]).

2.2. Label elements

Label elements:

Hazard statements:  H302: Harmful if swallowed.

H373: May cause damage to organs through prolonged or repeated exposure ([oral]).

Hazard pictograms:  

GHS07: Exclamation mark

GHS08: Health hazard


Signal words:  Warning

Precautionary statements:  P260: Do not breathe dust/fumes/gas/mist/vapours/spray.

P264: Wash hands thoroughly after handling.

P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor. P330: Rinse mouth.
P501: Dispose of contents/container to an authorised waste disposal contractor.

2.3. Other hazards

PBT:  This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures


Hazardous ingredients:

MONO ETHYLENE GLYCOL – REACH registered number(s): 01-2119456816-28

EINECSCASPBT / WELCLP ClassificationPercent
203-473-3107-21-1Acute Tox. 4: H302; STOT RE 2: H373>90%

DISODIUM TETRABORATE, ANHYDROUS

215-540-41330-43-4Repr. 1B: H360FD1-10%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact:  Wash immediately with plenty of soap and water.

Eye contact:  Bathe the eye with running water for 15 minutes.

Ingestion:  Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.
Inhalation:  Remove casualty from exposure ensuring one’s own safety whilst doing so. Consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact:  There may be mild irritation at the site of contact.

Eye contact:  There may be irritation and redness.

Ingestion:  There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation:  Absorption through the lungs can occur causing symptoms similar to those of ingestion.

Delayed / immediate effects:  Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment:  Not applicable.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media:  Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards:  In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters:  Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions:  Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers
leak-side up to prevent the escape of liquid.

6.2. Environmental precautions

Environmental precautions:  Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures:  Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

6.4. Reference to other sections

Reference to other sections:  Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements:  Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions:  Store in a cool, well ventilated area. Keep container tightly closed.

7.3. Specific end use(s)

Specific end use(s):  No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Workplace exposure limits:

Respirable dust

State8 hour TWA15 min. STEL8 hour TWA15 min. STEL
EU60125

Hazardous ingredients:

MONO ETHYLENE GLYCOL

Workplace exposure limits:

Respirable dust

State8 hour TWA15 min. STEL8 hour TWA15 min. STEL
EU20 ppm (Sk)40 ppm (Sk)

DNEL/PNEC Values


OPTICOOL ANTIFREEZE BLUE

TypeExposureValuePopulationEffect
DNELInhalation35 mg/m3WorkersLocal
DNELDermal106 mg/kgWorkersSystemic
DNELInhalation7 mg/m3ConsumersLocal
DNELDermal53 mg/m3ConsumersSystemic
PNECFresh water10 mg/l
PNECMarine water1 mg/l
PNECFresh water sediments20.9 mg/kg
PNECSoil (agricultural)1.53 mg/kg

Hazardous ingredients:

MONO ETHYLENE GLYCOL

TypeExposureValuePopulationEffect
DNELInhalation35 mg/m3WorkersLocal
DNELDermal106 mg/kgWorkersSystemic
DNELInhalation7 mg/m3ConsumersLocal
DNELDermal53 mg/m3ConsumersSystemic
PNECFresh water10 mg/l
PNECMarine water1 mg/l
PNECMicroorganisms in sewage treatment199.5 mg/l
PNECFresh water sediments20.9 mg/kg
PNECSoil (agricultural)1.53 mg/kg

8.2. Exposure controls

Respiratory protection:  Respiratory protection not required.

Hand protection:  Protective gloves.

Eye protection:  Safety glasses. Ensure eye bath is to hand.

Skin protection:  Protective clothing.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State:  Liquid Colour:  Blue Odour:  Odourless
Evaporation rate:  No data available.

Oxidising:  No data available.

Solubility in water:  Miscible

Viscosity:  Non-viscous

Kinematic viscosity:  21

Viscosity test method:  cP @ 20°C

Boiling point/range°C:  165                                                                       Melting point/range°C:  -12

Flammability limits %: lower:  No data available.                                                                            upper:  No data available.

Flash point°C:  111                                                              Part.coeff. n-octanol/water:  log Pow -1.93

Autoflammability°C:  400                                                                                 Vapour pressure:  0.05 kPa

Relative density:  1.13 @ 20 deg C                                                                                    pH:  No data available.

VOC g/l:  No data available.

9.2. Other information

Other information:  No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity:  Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability:  Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions:  Hazardous reactions will not occur under normal transport or storage conditions.

Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid:  Heat.

10.5. Incompatible materials

Materials to avoid:  Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products:  In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects


Toxicity values:

RouteSpeciesTestValueUnits
ORALRATLD507,712mg/kg
DERMALMUSLD503,500mg/kg
VAPOURSRAT4H LC502.5mg/l

Relevant hazards for product:

HazardRouteBasis
Acute toxicity (ac. tox. 4)INGHazardous: calculated
STOT-repeated exposureHazardous: calculated

Symptoms / routes of exposure

Skin contact:  There may be mild irritation at the site of contact.

Eye contact:  There may be irritation and redness.

Ingestion:  There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation:  Absorption through the lungs can occur causing symptoms similar to those of ingestion.

Delayed / immediate effects:  Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity


Ecotoxicity values:

SpeciesTestValueUnits
FISH96H LC5072860mg/l
Daphnia magna48H EC50>100mg/l
GREEN ALGA (Selenastrum capricornutum)96H ErC50>6500mg/l

12.2. Persistence and degradability

Persistence and degradability:  Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential:  No bioaccumulation potential.

12.4. Mobility in soil

Mobility:  Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification:  This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects:  Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations:  Transfer to a suitable container and arrange for collection by specialised disposal company.
NB:  The user’s attention is drawn to the possible existence of regional or national

regulations regarding disposal.

Section 14: Transport information

Transport class:  This product does not require a classification for transport.

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations:  Not applicable.

15.2. Chemical Safety Assessment

Chemical safety assessment:  A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information:  This safety data sheet is prepared in accordance with Commission Regulation (EU) No

2015/830.

Phrases used in s.2 and s.3:  H302: Harmful if swallowed.

H360FD: May damage fertility. May damage the unborn child.

H373: May cause damage to organs ([kidneys]) through prolonged or repeated exposure ([oral]).

H373: May cause damage to organs through prolonged or repeated exposure ([oral]).

Legal disclaimer:  The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.