Data Sheet: Classic Oils Anti-Freeze Safety
Compilation date: 05/03/2021
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: Classic Oils 2-Year Blue Anti-Freeze
Product code: N/A
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: PC4: Anti-Freeze and de-icing products.
1.3. Details of the supplier of the safety data sheet
Company name: Classic Oils Ltd
Building 96
The Lubricant Store Bicester Heritage
Buckingham Road
Bicester
Oxon
OX26 8AL
United Kingdom
Tel: 01869 227062
Email: sales@classic-oils.net
1.4. Emergency telephone number
Emergency tel: 01869 227062
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CLP: Acute Tox. 4: H302; STOT RE 2: H373
Most important adverse effects: Harmful if swallowed. May cause damage to organs through prolonged or repeated exposure ([oral]).
2.2. Label elements
Label elements:
Hazard statements: H302: Harmful if swallowed.
H373: May cause damage to organs through prolonged or repeated exposure ([oral]).
Hazard pictograms:
GHS07: Exclamation mark
GHS08: Health hazard
Signal words: Warning
Precautionary statements: P260: Do not breathe dust/fumes/gas/mist/vapours/spray.
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor. P330: Rinse mouth.
P501: Dispose of contents/container to an authorised waste disposal contractor.
2.3. Other hazards
PBT: This product is not identified as a PBT/vPvB substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
MONO ETHYLENE GLYCOL – REACH registered number(s): 01-2119456816-28
| EINECS | CAS | PBT / WEL | CLP Classification | Percent |
| 203-473-3 | 107-21-1 | – | Acute Tox. 4: H302; STOT RE 2: H373 | >90% |
DISODIUM TETRABORATE, ANHYDROUS
| 215-540-4 | 1330-43-4 | – | Repr. 1B: H360FD | 1-10% |
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: Wash immediately with plenty of soap and water.
Eye contact: Bathe the eye with running water for 15 minutes.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one’s own safety whilst doing so. Consult a doctor.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
4.3. Indication of any immediate medical attention and special treatment needed
Immediate / special treatment: Not applicable.
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
5.2. Special hazards arising from the substance or mixture
Exposure hazards: In combustion emits toxic fumes.
5.3. Advice for fire-fighters
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers
leak-side up to prevent the escape of liquid.
6.2. Environmental precautions
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
6.4. Reference to other sections
Reference to other sections: Refer to section 8 of SDS.
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.
7.3. Specific end use(s)
Specific end use(s): No data available.
Section 8: Exposure controls/personal protection
8.1. Control parameters
Workplace exposure limits:
Respirable dust
| State | 8 hour TWA | 15 min. STEL | 8 hour TWA | 15 min. STEL |
| EU | 60 | 125 | – | – |
Hazardous ingredients:
MONO ETHYLENE GLYCOL
Workplace exposure limits:
Respirable dust
| State | 8 hour TWA | 15 min. STEL | 8 hour TWA | 15 min. STEL |
| EU | 20 ppm (Sk) | 40 ppm (Sk) | – | – |
DNEL/PNEC Values
OPTICOOL ANTIFREEZE BLUE
| Type | Exposure | Value | Population | Effect |
| DNEL | Inhalation | 35 mg/m3 | Workers | Local |
| DNEL | Dermal | 106 mg/kg | Workers | Systemic |
| DNEL | Inhalation | 7 mg/m3 | Consumers | Local |
| DNEL | Dermal | 53 mg/m3 | Consumers | Systemic |
| PNEC | Fresh water | 10 mg/l | – | – |
| PNEC | Marine water | 1 mg/l | – | – |
| PNEC | Fresh water sediments | 20.9 mg/kg | – | – |
| PNEC | Soil (agricultural) | 1.53 mg/kg | – | – |
Hazardous ingredients:
MONO ETHYLENE GLYCOL
| Type | Exposure | Value | Population | Effect |
| DNEL | Inhalation | 35 mg/m3 | Workers | Local |
| DNEL | Dermal | 106 mg/kg | Workers | Systemic |
| DNEL | Inhalation | 7 mg/m3 | Consumers | Local |
| DNEL | Dermal | 53 mg/m3 | Consumers | Systemic |
| PNEC | Fresh water | 10 mg/l | – | – |
| PNEC | Marine water | 1 mg/l | – | – |
| PNEC | Microorganisms in sewage treatment | 199.5 mg/l | – | – |
| PNEC | Fresh water sediments | 20.9 mg/kg | – | – |
| PNEC | Soil (agricultural) | 1.53 mg/kg | – | – |
8.2. Exposure controls
Respiratory protection: Respiratory protection not required.
Hand protection: Protective gloves.
Eye protection: Safety glasses. Ensure eye bath is to hand.
Skin protection: Protective clothing.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid Colour: Blue Odour: Odourless
Evaporation rate: No data available.
Oxidising: No data available.
Solubility in water: Miscible
Viscosity: Non-viscous
Kinematic viscosity: 21
Viscosity test method: cP @ 20°C
Boiling point/range°C: 165 Melting point/range°C: -12
Flammability limits %: lower: No data available. upper: No data available.
Flash point°C: 111 Part.coeff. n-octanol/water: log Pow -1.93
Autoflammability°C: 400 Vapour pressure: 0.05 kPa
Relative density: 1.13 @ 20 deg C pH: No data available.
VOC g/l: No data available.
9.2. Other information
Other information: No data available.
Section 10: Stability and reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong oxidising agents. Strong acids.
10.6. Hazardous decomposition products
Haz. decomp. products: In combustion emits toxic fumes.
Section 11: Toxicological information
11.1. Information on toxicological effects
Toxicity values:
| Route | Species | Test | Value | Units |
| ORAL | RAT | LD50 | 7,712 | mg/kg |
| DERMAL | MUS | LD50 | 3,500 | mg/kg |
| VAPOURS | RAT | 4H LC50 | 2.5 | mg/l |
Relevant hazards for product:
| Hazard | Route | Basis |
| Acute toxicity (ac. tox. 4) | ING | Hazardous: calculated |
| STOT-repeated exposure | – | Hazardous: calculated |
Symptoms / routes of exposure
Skin contact: There may be mild irritation at the site of contact.
Eye contact: There may be irritation and redness.
Ingestion: There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation: Absorption through the lungs can occur causing symptoms similar to those of ingestion.
Delayed / immediate effects: Immediate effects can be expected after short-term exposure.
Section 12: Ecological information
12.1. Toxicity
Ecotoxicity values:
| Species | Test | Value | Units |
| FISH | 96H LC50 | 72860 | mg/l |
| Daphnia magna | 48H EC50 | >100 | mg/l |
| GREEN ALGA (Selenastrum capricornutum) | 96H ErC50 | >6500 | mg/l |
12.2. Persistence and degradability
Persistence and degradability: Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential: No bioaccumulation potential.
12.4. Mobility in soil
Mobility: Readily absorbed into soil.
12.5. Results of PBT and vPvB assessment
PBT identification: This product is not identified as a PBT/vPvB substance.
12.6. Other adverse effects
Other adverse effects: Negligible ecotoxicity.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.
NB: The user’s attention is drawn to the possible existence of regional or national
regulations regarding disposal.
Section 14: Transport information
Transport class: This product does not require a classification for transport.
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Specific regulations: Not applicable.
15.2. Chemical Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
2015/830.
Phrases used in s.2 and s.3: H302: Harmful if swallowed.
H360FD: May damage fertility. May damage the unborn child.
H373: May cause damage to organs ([kidneys]) through prolonged or repeated exposure ([oral]).
H373: May cause damage to organs through prolonged or repeated exposure ([oral]).
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.